Solid quartz and/or agate geodes are, for the most part, safe for aquariums. Geodes with small crystalline lattices containing cinnamon colored or black crystals may contain metals and arsenic in trace amounts. Green coatings may involve copper minerals and should be avoided (especially in invert setups). Chalky inclusions should also be avoided since these may be anhydrous minerals that will become released once immersed in water. Large quartz/amethyst crystals should be OK. Just note that amethyst may fade over time under constant flourescents.