I suspect is sharizan right, silione alone will not take the pressure.
Better to put another pane of glass over the entire length of the crack and silcone it in.
And unless you have an old pane laying around, it may not be worth the cost on such a small tank.
But just to get experience learning to fix one, has a different type of worth/value.
I like to use 2 panes and sandwich the crack, but that's on much bigger tanks, 1 might work on that small one. (like this)