Get a chunk of the proposed rock and place into a 1 gallon container. Allow it to sit there for a few days. Purchase a feeder goldfish and add it to the container. If the goldfish is still alive 24 hours later, the rock is probably aquarium safe. This is the only reliable way to test, given the wide range of toxic substances which could be present. Use a fairly good size chunk of rock so that the limited, 1 gallon volume will concentrate whatever may be leaching from the rock.