Stingrays produce an incredible amount of ammonia..
How much water volume are you working with? What kind of filtration, primarily biological media are you using? How many rays? How much are you feeding?
Nitrifying bacteria only establishes as much as it needs to consume a constant amount of ammonia to the tank. When you suddenly and drastically increase the 'constant' amount of ammonia in the system, it will take 2-4 weeks for the nitrifying bacteria to re-establish itself. If you are doing LARGE frequent water changes to combat this issue, you are removing the ammonia which is the food source for the nitrifying bacteria.. By removing the ammonia so often, it is disallowing the bacteria to re-establish self at density you need in your biological media..
vicious cycle, or, pun intended, vicious not cycled..
The smaller the water volume, the more rays and food you have, and lack of surface area in the biological media, the worse the problem will be..
Pre-cycle the tanks prior to importation with raw seafood or ammonia. This will establish a larger than needed amount of nitrifying bacteria, and rather then re-establishing itself upwards to a larger amount, it will simply die off until it reaches it's designated amount. The other method is not feeding the fish upon arrival, and allowing the ammonia they produce just from osmosis to feed the nitrifying bacteria.. Use chemicals like Prime and Stability to neutralize ammonia/nitrite and speed up the bacterial process, but try to not do water changes so that the bacteria can easily and quickly establish itself. Thereafter, Slowly increase feeding schedule so that the nitrifying bacteria can steadily grow along side the new constant intake of ammonia.
Hope that helps!