I also have used lava rock, old toothbrushes, and anything else i find.
The whole mystique over biomedia is to me overkill and a lot of useless hype.
Biomedia is simply a surface for bacteria to form and grow biofilm on, and I doubt those bacteria care one way or the other what that surface is.
As long as oxygenated water can flow over and around it, it works.
And the idea that we aquarists need a ton of extra biomedia is also overkill, once enough bacterial biofilm forms to consume the ammonia and nitrite our fish population produce, a lot more won't work any better because that population density of bio-bacteria is dependent on its food supply, ammonia and nitrite.

At the moment I use a couple little bag of rings, a lava rock block, as biomedia and some Porrett foam that functions as both bio, and mechanical media.



The majority of my bio filtration is done in my sump by aquatic and terrestrial plants, like Vallisneria, lilies, and mangrove saplings.

That dark end on the left side of the pic above, is where the bio and mechanical media is, the rest of the 125 gal sump, dedicated to plants.
And below are the results of that minor biomedia, yet heavy plant filtration.




The first tube above left reflects pH Normal pH range reagent, 8 to 8.2 (my normal tank water pH always overwhelms the low range reagent tube)
The 2nd tube is ammonia results 0
the blue tint tube is nitrite, results 0.
And the last tube on the right is for nitrate, undetectable.