guppy;1367845; said:Burnt wood and wood ash are somewhere near 25% calcium carbonate and will Raise the pH of water it is kept in.
Tannin is mainly tannic acid and lowers pH, it comes from some barks, woods, and mainly acidic leaves like walnut.
Loubard;1368357; said:Scrub the loose stuff off with a metalic brush and you will be fine.