You can form glass into a bend while it is hot/cooling, but you can't simply take a pane of glass and bend it. I'm assuming that "bent" acrylic is made the same way - if you simply bent a large pane of acrylic and cemented it (I believe that is what they call the technique for bonding acrylic) to two vertical panes, there would be a ridiculous amount of torque/force acting on the seal.