Aside from several Rhamdia species and Pylodictis, there are a handful of endemic Ictalurus...very very similar in appearance to our more familiar channel and blue cats.
There are two species of Prietella, both blind, cave-dwelling species.
Probably the most fascinating Mexican catfish is Lacantunia enigmatica, the Chiapas catfish. Not described until 2005, it's not closely related to any other catfish in North or South America, its a truly weird species. Unfortunately, it's never been imported into the Aquarium hobby as far as I know...