How long has the sand been in the tank? How thick is the layer of sand in the tank? A drop in pH without any change in ammonia could mean soft water. Have you ever tested the hardness out of the tap? My area has naturally soft water so I actually have to keep some crushed coral in one of my canister filters just to make it hard enough to buffer and maintain at around 6.8. Out of the tap my water is right on but without some sort of buffer the pH will drop like a stone.