Yup, just attach the tubing from your regulator (bubble counter) straight to the diffusor and thats it! Diffusors work fine for smaller tanks. Once you get over 30g, youre going to want to get an external reactor as they are more efficient for bigger tanks.
As for ph controllers, in my opinion, they are not necessary. all you really need is a few timers and a drop checker. using a timer, have your co2 turn on about 1hr before your lights turn on. also, have your co2 turn off 1hr before your lights turn off. with the drop checker, youll fine tune the flow of co2 until the color in the checker is a deep green / lime green color by the middle of your light schedule. once you get the hang of things, you'll see that a ph controller is a waste of money. i was planning on getting one at first, but after doing lots of reading, i saw that it wasnt necessary.
here's my co2 setup. the green tubing coming out of the bubble counter goes to my reactor. in your case, it would go straight to the diffusor. there's a small valve under the bubble counter to adjust the flow of co2.
oh, and youll need one more thing. some co2 gas in your bottle!!!
