I use a garden hose attached to my sink. I add about half of the dechlorinator during the fill and half after. *shrug* I haven't noticed any difference from when I added it all before, or even when I did it in each bucket before adding them. I think I would add it beforehand though if I were using water with chloramines instead of chlorine - not sure if it would make a difference, but I have heard that it takes a bit longer for the dechlorinator to work.