This may be of some help.
There are several types of glue used with acrylic. The main type and most common are solvent adhesive. They are available thickened and water thin. The water thin is used in common fabrication. It uses capillary action to flow between the pieces of acrylic. The chemical is actually a solvent and breaks down the plastic surface, allowing the pieces to flow together. The solvent evaporates and you have a beautiful seam. We use methylene chloride, (MDC), as our solvent adhesive. We mix it with a small amount of another chemical that allows us to adjust for temperature. It is applied using an applicator bottle that has a needle tip. Edge preparation prior to glue application is of utmost importance. Your final seam will never be better than your beginning edge. We use a joiner to prep the edge for general assembly but a hand scraped finish used on our art quality work yields the best results.
The other glue is 2 part. Basically, 2 part uses a thick liquid material that is part acrylic and a catalyst to make the reaction that hardens it. It is much harder to use, messier and in my opinion does not give as long a lasting or strong seam on average. It is used most often in furniture manufacturing where seams are made using very thick material. Solvent adhesives are harder to use on thick acrylic. Acrylic often forms some gas as the solvent reacts. Usually it can escape to the side of the seam but at 3/4 to 1" and above, small bubbles may form.
For Polycarb you also want a solvent adhesive. (Lexan is a brand name), It has a tendency to absorb moisture. The moisture interferes with the gluing and heating process. It tends to make the seams turn white and will boil in the plastic if heated incorrectly. Fun stuff huh? We hate to fabricate polycarb. We do bend it with good results in 1/8" and 3/16". You have to be very careful at 1/4" and cross your fingers any thicker. Heat slow and flip the piece over often. It takes a long time to heat and cools in a couple seconds. It's easy to burn the surface before you get the center hot.
For solvent adhesives, I recommend Craftics Inc. They can ship them. We do not have a haz mat license. For polycarb you want to us weld-on #4. For acrylic, you can use weld-on #4 or #5 You will also need an applicator, smallest needle diameter, 16 gage or the water thin solvents. We think the 2 oz bottle is easiest to handle.
Craftics web site is
http://www.craftics.com
For other fabrication information, try
http://www.Cyro.com
They have fabrication manuals available and will send them to you or tell you where you can get them. If in Arizona, Curbel plastics in Phoenix has them.
I would say they ran a little light on the solvent in that area, and if the mark is growing it will split. Fortunately you only have to run the solvent on the edges for it to weld it back together.