I know all about DOC's and VOC's, and beleive me I've had problems with both. However, with this setup, if you stir your DSB every three or four weeks you can avoid the potential time bomb that is organic compounds. Stirring your substrate allows the "organics" to be released into your water column where the canister pads will trap them. You just have to clean you canister after stirring the sand bed. DSB's can potentially turn into a disaster, but if well maintained they are beautiful things. From my expeirience anyway.