New York's Silurian shale deposits are, for the most part, compressed siltstone which is safe in aquaria. A few deposits are more associated with coal than the usual association with natural gas deposits. Check the pieces from coal bearing deposits for any signs of metallic ores. Some some shale fossils are replaced with galena, pyrite, and molybdenite. These pieces should be left out of the aquarium since their replacement is lead based.