http://www.monsterfishkeepers.com/forums/showthread.php?t=106053&highlight=atlantic+ray
Heres a recent thread I made on the topic..
The problem is that, for in order to have a saltwater organism adapt to freshwater, like an atlantic ray or bullshark.. it must release an inordinate amount of ammonia and urea to counter balance what happens internally with their osmosis system.. I think that if they were unable to process water through their body in this way, the urea content in their blood would rise and kill them. ~ Not exactly sure, but something to this effect.
The other issue is, the higher the pH the more toxic ammonia is.. with these fish originating from the ocean and a pH of 8.5, it makes it hard for them to stay healthy with their own ammonia output, and need for higher pH. Ammonia toxicity at a pH of 8.5 is a thousand fold of the toxicity at a pH of 6.5.. When converted to FW, the pH must till stay high, or they will simply die.. If you try to lower the pH to combat the ammonia toxicity, it becomes very counterproductive and stressful..
So, in order to keep em happy.. you need a large volume of water to dilute the ammonia, and a great filtration system with a higher turnover rate to process that ammonia.. and without frequent water changes or a drip system, the nitrates will climb so rapidly that it can cause even further problems..
Don't get me wrong, they can be kept in home aquaria.. but their needs are hard to meet if all of that made sense. They would do best in something of 600g+, drip system.. or public aquarium.. or leave em in the ocean, where they belong.. (or river)