you first need to decide what type of tank you want to have. fish only (FO), fish only with live rock (FOWLR) or a reef. the fish you want or do own will affect this. puffers dont normally make good reef fish as they like to investigate things with thier teeth. mainly all your expensive corals. there are exeptions though. my puffer isnt at all interested in my corals.
going fom brackish to marine is easy enough. i used all the same equiptment as before, but you may have problems with your canister filter. they become nitrite factories if maintainance slips. they need to be cleaned regularly, maybe even twice a week so stop this. for a FOWLR or FO its not too much of of a problem, but you will get an awful lot of algae. for a reef it can be harmful to corals if the levels become too great.
i'd also push to 1.022 and then get some live rock. or a 60/40 live/dead mix, it will greatly improve your filtration. and some reef inverts as a clean up crew to help with your duties.
triggers in general are a messy fish, not to mention grow quite big. the most suitable one for you i think is the niger trigger. but will still be cramped in your tank with your other fish. they will also move around your decor to thier liking too. so you gotta make sure its all solid.
i think the clown route will be good as they stay small. but remember that clows are damselfish in pyjamas, and damsels are basically cichlids of the SW world. so i would add them last. other fish such as firefish, some gobies jawfish dottybacks and wrasse will be a good call too. just do your research as not all these fish are reef safe. a dwarf angel would be nice in there too, but they need loads of rock to pick algae off, and only one per tank as they will scrap to the death.
check the SW forum too. there is loads of info there and more people who now more than me about the whole marine thing. ive only had my tank as marine for about 6 months. learning quick though...