I've used 2 different products for in tank backgrounds and both were made by Quikrete, one was Quikrete Quikwall Surface Bonding Cement which is a fiberglass reinforced Portland cement and the second was Quikrete commercial grade Fast Set Repair Mortar.
I also used Quikrete liquid cement color to tint or color the cement to the color I wanted.
Do be aware that if you use a cement product to create a background or decorations for your tank, you will need to 'cure' the cement prior to adding living things to your tank. I soaked my backgrounds in a large tub for a couple weeks or so once the cement had set up, changing water every few days until the pH of the water dropped considerably.