I personally beleive that you can have enough biological filtration, however extra won't hurt. You are only going to have enough bacteria growing to consume the amount of waste in your tank. Which i why a focus on Mech after my bio is at a suitable level.
With that said, bio balls i think benifit more from being at lest partly exsposed to air. I've seen them listed as 160 sr. ft. per cu. ft of materail.
This is from seachems site " Matrix™ is a porous inorganic solid about 10 mm in diameter. Each liter of Matrix™ provides as much surface (>~700 m2) as 170 liters of plastic balls!"
So this has a lot more surface area. Also if it's for extra you could use, De-nitrate from them"
For best results, de*nitrate™ should be placed to assure the flow of water through it, such as in a canister filter, chemical filtration module, or box filter. Flow rate should not exceed 200 L (50 gallons*) per hour. If higher flow rates are unavoidable, use Matrix™ or Pond Matrix™. It is best to rinse off dust before use. Once de*nitrate™ has been in use for several days, nitrate concentrations should start to fall and level off gradually at a concentration of about 4–5 mg/L as nitrate. As long as nitrate concentrations remain under control, the product is not exhausted. Each 500 mL of de*nitrate™ treats about 100–200 L (25–50 gallons*), depending on initial nitrate concentration and the current biological load. Enough should be used to remove nitrate at a rate at least as fast as the rate of formation. If very high nitrates are initially present, they should be brought down to less than 20 mg/L with water changes."