With an average size of 6" there is a distinct possibility Pimelodus pictus would be over powered and swallowed whole by any ray species over 8" (20cm) disc. This species not only have very sharp reversed barbed pectoral and dorsal spines they also have a toxic venom on these also. If anyone has felt the pain from one when trying to release it from a tangled net they will know exactly where I'm coming from. This is not a strong enough toxin to kill a ray it would just cause discomfort, its the fact it could easily choke due to locking the fins in a outward position thus becoming lodged in the throat cavity.
I much safer choice would be its larger cousin Pimelodus blochii. This Catfish is very variable regarding pattern, some are stunning! what they all have however is a distinctive spot beneath the first ray of the dorsal fin(hard ray)...check them out, these generally grow to 10" in captivity, its possible for them to get a little larger but if I said 12" I think that would be a little ambitious.
Lovely Cats and relatively cheap to buy, look great in a group, go into a feeding frenzy just like pictus when they detect food, very excitable characters.