As someone who has run pipe, run tubing, run electrical conduit (PVC, aluminum tube, galvanized pipe, and PVC pipe), let me save you some time. It takes YEARS to truly understand all the ins and outs of running pipe/tubing--I did it for 3-4 years, and I never became truly skilled at it. What we do with these fish tanks is very simplistic compared to what real pro's do.
The "right way to do it" is much easier to communicate than the reasons why it is right, and people who know don't want to "rebuild the wheel" by thinking it all through to explain it.
So realize that whenever you try to improve on "the way it's done" with pipe/tubing/conduit and all the fittings and sizes and thread types......you're trying to improve on solutions that have been devised and improved on for hundreds of years by true masters of the craft. By men who achieved a level of proficiency with these things that few of us will ever appreciate, much less develop ourselves. And have decades of trial and error on their side, and decades of feedback from open markets. Pipe/plumbing/tubing fittings are engineering marvels that undergird civilization--among the highest achievements of humanity. It's that big of a deal. So, unless you're DaVinci or Archimedes, or Robert Manning, you probably aren't coming up with anything new.
As for why they don't make a bulkhead that can accept half of a pipe union.....think about it....why would they? they make a bulkhead with female NPT threads, that can accept a male NPT fitting or nipple. So you just buy whatever kind of union you want to have, with whatever connector type you want, to fit into the bulkhead. Choose from a PVC union that is Slip by Male Pipe Thread, or Slip by female pipe thread and a threaded nipple, or Slip by Slip and just glue a short piece of PVC pipe that is effectively a "slip nipple" , or.......etc, etc, etc.
There are a BUNCH of different types of PVC unions out there for you to choose from, so just choose one that fits in a threaded female NPT bulkhead fitting. Or a slip fitting. But, please, PLEASE, don't ask that they invent yet ANOTHER type of plumbing fitting. There's enough different ones out there, already.
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If I were you, I'd buy my plumbing fittings locally, at a local store you can drive to and look at fittings in your hand, and return ones you don't use. If you don't run pipe all day everyday, you'll need to do some trial and error to get the right fittings to do the job.