Substrat Pro would work well in a sump. The way I suggest you set it up is to have the Substrat Pro near the bottom of the sump chamber so it is fully submerged, and to have the bio balls above it. The bio balls need to be exposed to the air to work properly, the water should just drip through them without submersing them. The foam mat should be on top of the bio balls, and I would put filter wool or similar on top of the foam.