The gallons of sump, or even amount of media stuffed in it, are not as important as the biofilms access to aerated conditions in the water flowing by.
Just because a sump is packed with media, is not es important as the flow conditions that allow the bacteria access to ammonia passing by. These beneficial bacteria are aerobic, and oxygen is one of the determining factors in their ability to consume ammonia and nitrite.
Just as the size of tank may not be as important as the amount of stock in it.
Bacterial populations will be determined by the food supply offered.
Just because a sump is overstuffed with media, that bacterial population will not be more than the food supply provided by the fish.
Of course if the tank is overstocked, there must be enough media to handle the load, but the conditions need to beaerobic enough to allow a robust bacterial populations ability to feed .
Your testing of water parameters is the only real way of determining if your filter is doing its job, (barring disease or death from ammonia poisoning).
I have run 500-600gallons of fish tank(s) on a 50 gallon sump with only a few mesh bags of media laying in the path of a well oxygenated flow, or a small (in comparison fluidized bed reactor) and tests indicated 0 ammonia.

The 4 ft tall fluidized bed (left) contained only a few lbs of moving media, and the barrel a few filter socks, and gear like pump, and heaters, and and was in line with about 500 gallons of stocked aquariums. (that said, one tank in the line was a heavily planted overhead refugium (terrestrial and aquatic plants) used to help cope with nitrate)

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