TPO is used on a lot of "green roofs" now days but I don't know if that makes it fish safe. I'll be keeping an eye on the responses to this I have access to a roll of TPO and was thinking about using it for a pond liner.
Did some research on TPO "Thermoplastic Polyolefin".
What I found is Polyolefin is used a lot in food packaging. The only hazard is if its heated or melted it can result in hazardous fumes and/or gases.