Yes, they excrete a lot more urea/ammonia in freshwater (not sure about 10X but certainly a lot more). Under conditions of increasing salinity they store the urea in their plasma and tissues to maintain osmotic balance with the surrounding water. In FW they just excrete it all out to maintain relatively low plasma osmolarity.
I imagine that you would need a large tank with a very good filtration system to successfully keep these guys in captivity. I'm sure it can be done but would be a much more difficult setup than for Potamotrygons, so most people who try to keep them probably don't provide appropriate conditions.
I think your best option would be Antenna rays ( Plesiotrygon Iwamae). They can be tricky to keep but the husbandry issues are probably easier to overcome than for some of the other options. I believe they are currently available from Aquascape, but given that they look quite similar to some Potamotrygon species you should probably check with your local authorities to make sure you can legally keep them.