Make sure you see them filled and not leaking. Watch for bowing. Look across the face of the tank longwise, like you're aiming a rifle, and you should only see a very slight bow. Scratches and yellowing are usually considered more cosmetic than structural. That's all I've got.
Glass:
Examine the seals very closely and look very, very closely for tiny cracks. Small chips are usually okay on corners, but if the chip is half the thickness of the glass, or very wide, pass on the deal. Also, I like to push very gently at the silicone seal and make sure my fingernail doesn't slide right under it.