I'd get the ph stable with ro water for at least a month before adding fish(you can add tetras etc. to cycle) even with a cycled filter, as long as you didn't dry the filter out.
40g is a little small for 5 discus, which would be a minimum as they like to be kept in groups, you could grow smaller ones out in this tank but you'd need to go bigger if you wanted them to thrive and possibly breed later on