Well I had been using purigen for about six months and once it expired, I didn't re-charge it and threw it out. I also neglected on vaccuming my gravel for a while. As a result I now have high spikes of ammonia 8 ppm, lower spikes of nitrite 0.5 ppm and high nitrites 40 ppm. My question is, is my tank re-cycling because I stopped using purigen or am I having spikes because of the build up of organic waste in my tank? Woudl this clear with a large 40% water change ?