I've dumped plenty of WC fish straight into the tank, no problem. I know importers that have dumped thousands of WC fish straight into their tanks, no problem.
Temp changes are generally a non issue, unless off by a very wide margin, and most shock is caused from going warm to colder, than cold to warmer. Again, if/when a fish dies during an acclimation period, it's from stress, or osmotic shock, the former being caused from potentially numerous factors, including on how it was originally collected and housed, the latter generally being caused from a large shift in TDS. Many people used to. and often still do, refer to this as pH shock, which is a misnomer.
If ones TDS shifts too quickly it can cause osmotic shock, which for many years hobbyists confused with pH shock, only because most hobbyists don't own a TDS meter.
Osmoregulation has nothing to do with pH, and everything to do with controlling the balance of water/salt concentrations. pH has nothing to do with regards to if ones water is a hypertonic solution, hypotonic solution, or if it's isotonic. The shock part of the equation comes in when a fish has difficulty reaching equilibrium. The "high to low" shift in TDS values becomes more dangerous as the fish cells can become flooded with water faster than they can reach equilibrium, and burst .... which is where the term "shock" comes in. The biggest issue with pH is ammonia toxicity, as at higher pH values free ammonia can be much more lethal, especially when higher temps are involved.
Some additional reading for those interested.
http://www.angelsplus.com/ArticleOsmosis.htm
http://www.mtfb.com/MTFBJUNE/MTFB2 pages/jacobsarticle2.htm