Thanks for the input! Do you think 1/8" is sufficient? I was going to go 1/4"...I did find a source for type 1 (the good rigid stuff, not foam core) in black but was not able to find the 2x2" extruded angle strips to glue the corner seams in black. I figured I would just tape off and spray the corner strips with black. krylon fusion when it was finished...I like the idea of mounting the pvc sheet to the plywood first but then how would I mount the plywood to the tank frame without drilling holes through it?
Sorry, I forgot to mention that you'd have to use pocket holes in the lumber itself. The screws woud then toe-nail through the lumber and into the plywood without puncturing the outer-most veneer and certainly not the PVC. This will be tricky with the stacked design as you'll have to start putting the plywood sheeting in place as you build the frame. I do have to admit in a tank your size this would likely be more trouble than it's worth.
And I suppose you once you get a piece of plywood to fit you could always transfer those markings to a sheet of PVC. You know, thinking out loud here, that would probably be what I do.
I'd also take care to try to keep the plywood box that comes together inside of the frame more straight, square, level, etc. than the lumber framing itself. If you have an area that is really far off you may have to try to shim the plywood out as you go.
As far as the thickness of the PVC, I think I mentioned earlier that that's 125 mils thick, or 125 thousandths of an inch.
A layer of 6 ounce fiberglass cloth is about 4 mils. So your 1/8" PVC would be about as thick as 25 layers of wetted out fiberglass plus a gelcoat surface.
Did you read the recent thread on the FRP sealed plywood tank? Interior edges were sealed with polyurethane caulk. FRP comes in smooth surfaces and lots of colors. I haven't priced it in a few years, however.