I agree that they have different builds and headshapes. Also juvenile coloration patterns are different. I think intermedia, piquiti, Melanie, and tems have similar shapes are somewhat simila juvenile coloration while orino, kels, monos, and ocellaris are similar. I’m no taxonomist so take my observations with a grain of salt.
The casiquare river I believe acts like a canal between the rio inirida and the rio Orinoco or something like that so they may overlap. Better to let the pros chime in.