Depends how many curviceps you decide to go with. Also, if you're still planning the tank and size isn't written in stone, a bigger tank would give you more possibilities.
But I kept them with a pretty good variety of SAs, including angels, discus, microgeos (rams), Apistogramma, and Mesonauta in well planted tanks. In a smaller tank, a couple of smaller growing angels would be a possibility imo.
I don't know how well I can describe them vs. other Laetacara. They can vary some according to mood and population. Probably some in the hobby have been mixed. I say mine were true curviceps, but only because I trusted the source, which was pretty knowledgeable when I had mine, but in reality I couldn't prove they weren't fulvipinnis, for example. I know they weren't dorsigera.
This might be helpful in a general way and up to a point; as I say, they can vary in different moods and according to where they're collected. So short of finding a scientific description and counting scales, etc., you're somewhat dependent on having a reliable source and taking their word imo. To a degree you can do a process of elimination, so I knew mine weren't dorsigera and weren't araguaiae, beyond that I trusted what the seller told me.