The idea of having predation like that doesn't sit well with me. It seems s bit warped to want to watch that in my opinion.
Are there some South Americans that won't hybridize?
South Americans are not the ones with the hybridization problem... Most of the time. In the Americas there are several different tribes of cichlid:
Astronotini (oscars)
Cichlini (peacock bass)
Retroculii (retroculus)
Geophagini (eartheaters, rams, apistos, pike cichlids)
Cichlasomatini (acaras)
Therapsini (all central american cichlids + umbees, caquetaia, heroina, australoheros, and mesoheros)
Heroini (discus, uaru, severums, angels, chocolates, true parrots)
Under some descriptions heroini is debatably lumped under therapsini.
I'm missing a few (I think) but if I can't remember then no one is going to remember.
Everything in therapsini (under the presumption that Heroines are not a part of that group) can hybridize and produce fertile offspring. I'm sure certain species in more derived lineages of other tribes can hybridize within their genus but other than that you can keep an oscar with a peacock bass without worrying about them producing some unholy chimera.
That said, for a 75, your options for a single fish that will fill out the tank are:
Convicts (Amatitlania nigrofasciata/siquia/kanna)
Amatitlania septemfasciata
Amatitlania myrnae
Amatitlania sajica
Amatitlania nanolutea
Rocio spinosissima
Herotilapia multispinosa
Any Cichlasoma (Cichlasoma proper... the black acaras)
Any Andinoacara (excluding green terrors)
Any Australoheros
Any Cryptoheros
These would fit size wise but they are also social:
The entire genus Thorichthys
Gymnogeophagus
Cribroheros longimanus
Biotodoma
Cleithracara
(The latter two would probably fit better as a group)
My immediate recommendation would be sajica or Australoheros. They fill out the tank and are very personable.
Glad I got here before Duane comes and posts a bunch of pictures saying CA cichlids can't fit in a 75...