I read it. as always he comes with excellent sources. BUT.... my point is that if it was such a concern then why does every major manufacturer put tempered glass on the bottom of the tank? surely there'd be more failures of the spontaneous variety.
when I redid my 150g the bottom was 1/2" thick tempered glass and it took quite the forceful impact to break it out. I replaced it with 1/2" tempered. it is a marineland tank, the one I told you about.
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· Breakage due to nickel sulfide (NiS) inclusions
Nickel sulfide inclusions are small polycrystalline spheres with a metallic appearance generally ranging from 0.1 mm to 2 mm in diameter. Sulfur is present in the raw batch materials in the form of sodium sulfate. Traces of nickel could also be present in the other batch material or could come from machinery that contains nickel-bearing alloys (i.e. stainless steel).
If sulfur ions and nickel ions are present in the batch material, there is no certainty that nickel sulfide will form. However, if this type of inclusion goes through a phase transformation from an alpha to a beta phase under a specific combination of time and temperature, there could be a change in crystalline structure, accompanied by a volume expansion of slightly over 2%. Although this volume change is slight, if the inclusion is located in the central tensile region in tempered glass, it can cause the internal tension stress to be released. The result is spontaneous breakage of the tempered glass into small fragments.
In conclusion, the requirement for a nickel sulfide stone to cause spontaneous breakage of a tempered glass can then be summarized as follows:
¨ Nickel, derived from trace amounts in the sand, firebrick or machinery must be present.
¨ Sulfur must be present.
¨ A rare crystalline from of nickel sulfide must occur.
¨ The rare crystalline form must end up in the center of the ribbon thickness as the ribbon of glass leaves the tin bath.
¨ That part of the glass ribbon in which that rare stone occurs must be made into a tempered glass.
¨ When the rare form of nickel sulfide undergoes transformation, it must develop sufficient additional tensile stress so as to exceed the tensile strength of the glass at the break point.
As mentioned above, all of these must occur, not just one, or two or three of them. Thus, the actual occurrence of a break caused by a nickel sulfide stone is an extremely unusual event, not an ordinary one.
so this is my main take away …. " the actual occurrence of a break caused by a nickel sulfide stone is an extremely unusual event, not an ordinary one."