My advice for what it's worth (it and $2.59 will buy a cup of coffee at Denny's), is to knock off the massive water changes!
Unless you are facing a crisis, like an ammonia spike, changing more than 20% of tank volume does as much harm as it does good. As has been said several times in this thread and on so many others in this forum a key to water parameters is stability.
You are much better off doing a 25% change initially, then follow that up with several smaller 10% to 15% volume water changes (do several in a day or two). Most rays aren't as fragile as people make them out to be unless you're dealing with Tiger, China and Ceja Rays with the exception of all stingrays susceptibility to ammonia and nitrate. You run a greater risk of "shocking" not only your rays but any tank mates with continuous high volume water changes.
Point is, just like when you acclimate a new fish to you tank you want to do it gradually, same premise holds true with water changes. Do it slowly and you will get a better result.