Stingray venom is a complex cocktail comprised of a variety of polypeptides and enzymes. Some, especially the ones that trigger a pain response, do degrade when subjected to heat that will not damage flesh. However, not all the components are going to degrade at these relatively low temperatures. Don't forget, human flesh is also primarily made of proteins (and water) and those proteins don't degrade in water that isn't hot enough to cause more damage to the victim than the original sting.
Freshwater ray stings tend to cause more tissue necrosis than marine rays, and the enzymes that cause the necrosis are less susceptible to heat degradation than the proteins that trigger the pain and inflammation responses.
Freshwater ray stings tend to cause more tissue necrosis than marine rays, and the enzymes that cause the necrosis are less susceptible to heat degradation than the proteins that trigger the pain and inflammation responses.