If you have a sump already, adding more media isn't gonna help. If your ammonia and nitrites are both at 0, then you already have all the media you need. Adding more media won't grow more bacteria, it's just a waste of space.
And if you did need more media, I'd go with something like pot scrubbies before using a big chunk of rock because it would have a very poor surface area. You can actually test this yourself.
Get a container of water, and fill it to the rim. Grab your chunk of rock and put it in, noting how much water it displaces. Now, do the same thing with a bunch of pot scrubbies that have a mass roughly the same as the rock. Note the amount of water displaced. Almost none right? The one that displaces the least amount of water will have the most surface area, and will be more efficient for growing bacteria.