Sintra should be fish safe. I've never used it for fish, but I have a cage made out of it for some of my snakes. A similar product, anyway- not Sintra by name, but same deal. It's expanded PVC. Do a google search for "PVCx" and you should come up with some info about it.
It's used for reptiles and amphibians all the time, and is a great product. I've never seen it used for fish, but I've seen it used for tons of amphibians, including Dendrobates (dart frogs), and those are extremely sensitive to chemicals in the water. The only issue with it is that it's soft like acrylic. If you go with this, I would suggest PVC welding corners instead of siliconing. A PVC weld will be MUCH stronger. You could put silicone over the PVC weld, but I wouldn't do just silicone.
Sintra is VERY strong, depending on the thickness of the product, but I'm not sure I'd trust it to build an aquarium out of it. I'd definitely reinforce seams from the outside with a frame at the very least.
Also, Sintra is really nice, but it scratches. It's basically going to be an acrylic tank, so be careful cleaning it! Any scratches are going to make a great place for algae to grow.