I believe acrylic aquariums retain heat much better than glass, but not sure why it would be that much higher than ambient air temp. It also seems a little odd to me that PH has been rising unless the substrate has carbonate minerals in it(lava rock should be inert). It sounds like you have really good conditions for cycling the tank, and I don't have any other ideas. Just for reverence here is a chart that shows the relationship of ph and free ammonia. There is a point where ph is too high for for nitrosomonas and nitrobacter, ph between 7 and 8 is "ideal" for both.