If you have small fish (just a few inches), dropping into ice water works pretty quickly. Just fill up a container with LOTS of ice and then enough water to immerse the fish. Once you let the water chill for a minute you can drop them in. They go into shock pretty quickly and die in 30s-1min in my experience. I don't know how well it would work on larger fish, but little guys have so little body mass that they tend to get cold very very quickly and die as a result.