I used 3 capfuls when I changed out the water in the 90g.
edit* if that’s the case then I should have use between 5-6 capfuls of prime instead of the measly 3 capfuls I used today.
If each capful is still 5ml, then 4 capfuls would have been plenty. Even still, 3 capfuls shouldn't have caused that kind of sudden death in your fish? At the most, you might have suffered a small ammonia spike once the chlorine and ammonia split. BTW - I have always treated for the entire tank volume, with Prime and with Safe.
I don't know anything about black fluorite sand, but I would be suspecting that before an underdose or overdose of Prime.