I'd love to get a solid answer on this one, but it seems to be like the butter vs. margarine debate in that it won't be solved for quite some time.
Personally, I'm using the Fluval carbon that came with my 305 canister right now to help get the BB in the tank started and to remove the ammonia/nitrates/nitrites, as I've read it can do. I've also heard that carbon, depending on quality, can break down within weeks or last up to three months. I'm sure there are many variables, though. Once the BB is set up in the BioMax media and the water levels "level out", I'll be removing the carbon and adding more BioMax.
Side note: I use cheap carbon on the bottom of my corner/box filters in my smaller tanks and have never had problems with the carbon leeching out harmful chemicals.