DO NOT use copper on any tank which has a shark in it.
i advise you to rehome your coral cat as soon as you can, the 65 gallon is going to kill it.
also, the puffer is a terrible tankmate for the shark. what are the dimensions of your tank?
Alco is right. Copper (in any form) + sharks & rays = death. Some idiot at a local aquarium (Moody Gardens @ Galveston Island) dosed their shark system with copper and killed 17 sharks in 48hrs.
More likely the puffer will eat the shark. Catsharks are sitting ducks to anything with a beak. (ie puffers & triggers) but yeah . . .either way. . .bad idea.