I am almost sure the reason behind these deaths was a crash in Ph. The damage to the underside of the disc is typical of this, this is extreme ammonia burn caused by a breakdown of the nitrogen cycle due to the bacteria being subjected to a low Ph value. Nitrification ceases to function or at least is vastly reduced at a Ph of 5 or less, check your Kh, if this is reading low then it shows there isn't enough mineral content present in your water, crushed coral and Cockle shell is a great buffer to add to the filter, never add this to the substrate as its far too abrasive for the rays underside. My water as for some reason started to come through the tap much softer recently so I personally add bicarbonate of soda with every water change to keep my Ph just above neutral (7.0).
Because freshwater rays are heavy feeders the filters have to work much harder than say a tropical tank housing general tropical fish so if you have a low mineral content it is likely the Ph is unstable between water changes, many use the constant drip system which overcomes this.
Hi Richard
I do 2 water changes a day through HMA and live in a hard water area. I have not noticed any drop in PH. Do you think i should still add some crushed coral to my sump to be on the safe side or will this actuall raise the PH even further? I am already at about 7.4 from memory.
Typically you add coral when your source water has a low PH to bring it up to a more stable level. If your PH is already over 7, you don't need to add coral as it can raise the PH increasing the toxicity of ammonia.