Did you have to lay the tank on that side to make the fillet? or was the calcium carbonate powder hold it together enough to keep it from dripping?
Yup, I put the tank on it's sides diagonally to pour the fillets.

A heavy 8 ft x 5 ft tank like the one your designing might be too difficult to maneuver though. It could also fall apart or crack the seams under it's own weight if it's not braced enough. So you should probably avoid putting stressful loads on the corners like that, if you're not sure. You could use MAX BOND THIXOTROPIC for corner fillets since it won't sag or drip. Or you could just fiberglass the corner seams, which is probably the easiest way to go. Or do both. Applying Max Bond Thixotropic would be more difficult. You'd need to load it into a caulking tub, large syringe, or pastry bag, apply it to the joint, then smooth it out with a filleting tool (or the back of a spoon.) It could get messy, but I've seen it done. Polymer Products has a nice tutorial on how to build a 220 plywood tank using Max ACR and Max Bond on their ebay page. Here's the link: http://www.ebay.com/itm/EPOXY-RESIN...438?pt=LH_DefaultDomain_0&hash=item33821b5cee