Lava rock won't work in that concept, but Pond Matrix will! Most lava rock is closed-cell, which means water doesn't reach below the surface. For anaerobic bacteria to grow, you need to get water/nutrients to the middle of a medium that has been deoxygenated by the aerobes on the surface. That usually means the first inch or so will not be anaerobic. So very fine and large sponges, thicker biomedia that can exchange water slowly and fine sand are some examples where nutrients get through the aerobic layer and into an anaerobic layer. I like sand because it's cheap. Playsand works well and only costs about $3 per 50 pound bag. It takes a few months before there is enough mulm in the lower levels of the bed to feed the anaerobes, but it's almost 0 maintenance since you can't stir it. I have only Malaysian trumpet snails and blackworm in mine and that helps to sift mulm into the deoxygenated areas to feed the process of nitrate reduction. Do some googling on Freshwater Deep sand bed, but realize it's a lot easier than some reads make it seem. I've gotten good results in my 5g with only 1" of fine sand!