nitrifying bacteria at low pH

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I measured my tank parameters yesterday and found some horrendous readings so decided to try what I could as gently as I could.

The tank is a 350l with a sixteen inch Leiarius cat, synodontis decorus and small plecs. There are two internal filters (fluval 4 plus and fluval 2 plus with foam and ceramic media respectively), plus two externals (fluval 4 and an equivalent, both filled with foam and a lot of ceramic media). There is a 1000 lph powerhead with air forced into the verturii with an airpump.

Temperature is 24 deg C. Decor is mopani wood and pea gravel one to two inches deep.

I'm using a aquarium pharma liquid test kit, not to plug it but I trust the readings due to use on tapwater and the other freshwater tanks (nine of 'em).

Readings yeaterday were ammonia 4 - 8 mg/L, nitrite zero, nitrate 20 mg/L, pH 6.0 or below (lowest test kit range) and KH was not measureable on the low end (1 drop to yellow end point). My tap water yesterday was zero for ammonia and nitrite plus 3 mg/L nitrate, pH 7.0 (buffered by water company). Also no measureable KH.

I have been playing with the 50L barrels at tank temp under areation and have found that a bag of coral gravel took the pH to 6.8 and 2dKH over a few days.

Knowing that a pH rise will with small water changes and added CaCo3 will certainly the fish at those readings I decided to go for broke and did an 80% water change with dechlorinated tapwater at pH 7.0 and no KH as it is from the tap. This was to get the ammonia down as far as possible (1 mg/L or less).

I did not disturb the filters apart from one external as they were producing a resonable flow rate and the bacteria (if there are any) would have enough of a pH shock as it was.

I took a media basket out of the fluval and moved the ceramic to another basket before filling it with coral gavel and aragonite sand in a bag. That's one of three baskets and I left the six sponges alone. There was not much evidence of bacterial colonies in that filter (slimy gunge is the good stuff). Suspect low pH has killed them off hence the ammonia being death on a stick high and no nitrite. Something in terms of nitrification must be happening because there was a moderatly high nitrate reading (20ppm) over the tap water (3ppm).

I'm going to have to watch this tank's water chemistry like a hawk. Daily checks, maybe twice per day.

Tested this am and found ammonia at 0.5 - 1.0 mg/L, nitrite 0.25 mg/L, nitrate 5 - 10 mg/L, pH 6.8 and KH 1 degree.

I'll have to change at least 50% again today to get the ammonia and nitrite down some more and keep doing this until there are some viable bacteria there. I am the filter! In can now change water with not too much disturbance to the fish right up one end of the tank (me).

When I did the 80% change I used a python to really hoover the gravel and an awful lot of mulm came out. That alone will not help the conditions.

Am not feeding for a day or two and after that only very lightly, depending on the water.

Aiming at pH 6.5 - 6.8, 3dKH.

There is massive aeration in the tank. Will add filter sponges from other tanks to help seed this tanks filters when parameters (pH) are similar.

I think that half of my problem is that my tank maintenance slipped for a few months (gravel hoovering) and I need a larger tank (pond) for this animal.

I think the pH drop killed off the filter bacteria. I've been trying since Christmas to put it right but unless I sort the water chemistry no end of water chnges will help, it will just build right back up again (ammonia).

There's a lesson to me. If, I'm not careful, I'm going to loose fish and I really hate that as it means I'm a **** fishkeeper.

Most of the help came from this thread, so thanks, you might be saving fish lives and you have made a difference to me!

I'll be using the CaCO3 idea in water changes when I can get the ammonia and nitrite under control. I have a barrel ready at pH 7.5 and 5dKH so I might use some of that today on this change along with filter squeezings for the baby oscar tank as the pH and KH should(!) be not too far apart.

Any constructive critisism will be welcomed!

This is worse than me flipping reef tank!

Best Regards,

Soggy

Have to do the reef tank first as there is new salt water in two of me barrels mixing since after cat tank water change...
 
now have ammonia 0.25 mg/L or less, nitrite trace, nitrate 5 mg/L, pH 7.0, 3dKH.

The pH wandered a bit when I added 150L of buffered water. Up to 7.2 then down to 7.0.

Seems to be a biological input as well as the pure chemistry from C02 from aeration as in my barrel only expts.

Interesting to see how it all changes with time esp ammonia, nitrite as these are nastier than they were now for the fish due to higher pH.

I want the pH at 6.5 - 6.8, might get there on it's own...

Might have to go through cycling all over again despite injecting filter squeesing from mature filters up the inlet pipes of the externals after a couple of hours (6hrs) from water change.

Only time and testing will tell me. Trick will be not to fiddle too much unless I have to.
 
not expensive aquarium buffer. Chemistry indicates about 15g CaCo3 should get me to 3dKH in 350L. Or 0.013g per litre will raise the KH by 1dKH.

If my maths is right! Test kit backs me up in the 50L barrel. Dropped a bit in the tank as sort of expected.
 
just some extra stuff about where I've been playing around with bog standard baking soda for real.

I made up a 'stock' solution of about 1g per litre of baking soda in tapwater in a 2L plastic jug and measured the pH as 8.2. Measured immediatly with no aeration, just stirring. This from a starting tapwater pH of 7.0. Remember pH is a log scale. That was liquid rock as coined above in terms of hardness. About seventy five degrees KH! It will raise the pH but not much.

I have to add that my digital kitchen scales are not very accurate on the 1g to 10g region so 1g might be 2g etc. Big errors, so using dilution and test kit to compensate. Well, wrong weight is wrong weight so I'm guesstimating using test kit at high dilution. Might be 2dKH instead of 3dKH in 200L of water.

Also you will notice that my quoted pH values vary in the barrels. This was down to how long i'd left it before adding buffer. Left alone in a clean container with no substrate my tap water with pH 7.0 and KH not measurable by my test kit, the pH will drop to 5.5. (borrowed a lab pH meter) over a day or so.

Scary.

All I can do now is watch the tank chemistry like a hawk and be ready to change water if the nitrogenous waste climbs or the pH or kH changes too much.

Before I did this second massive water change but after the first and replaced with buffered water I did put coral gravel and aragonite sand in an external filter basket (no other added buffer). The pH was about 6.8, up from five something before the first change (tap is 7.0 and KH not measureable). Next day the KH was just reading at 1dKH after adding the coral to the filter. The pH was unchanged at 6.8. It might work as a gentle way of moving the KH but I wonder where it will stop (KH) going up?!

Hopefully after reducing the ammonia still further to below 0.25 mg/L, setting KH to 3dKH the pH might stay put at around 7.0. If it drops slightly to the 6.5 to 6.8 range then great providing I can stop it there with the baking soda.

I'm probably going to have cycling problems as well.

I'll play honest and let you know if I loose any fish. They have taken a beating re pH shock but anything must be better than 8mg/L ammonia at pH 5.i don't know what. Battery acid cess pool.

Sorry for the long posts. Just thought I'd share the battle with you as board members are so helpful in general.

Regards,

Soggy:screwy:
 
So far, so good, early days...
 
I just looked at your link re basic water chemistry. I found it useful for aquaria and I've a degree in pure chemistry (shhh). Those things you never see nailed down in books...

Thanks!
 
the_deeb;1587933; said:
........
My question, is what do discus breeders (or other people who use low pH setups) do? I can't imagine there are constant ammonia problems in discus aquariums.

Daily large water changes. most of them are only using sponge filters.
 
Well the baking soda seems to be working ok so far. Thanks!

I was slightly concerned that there might be anti caking agents in the pot or other undesirable chemical apart from CaCO3. If there are there don't seem to be any immediate toxic effects to the fish.

The pH does jump about 0.2 pH units (7.0 to 7.2) when I add the 20g ballpark of baking soda to 200L of dechlorinated water. Tank (350L) pH went from 7.0 to 7.2 and I kept the 3dKH. Temp was matched to 24 dec C as in tank.

Did this water change due to a nitrite spike to about 0.25 - 0.5 mg/L.

Now have ammonia 0 - 0.25mg/L, nitrite 0 - 0.25mg/L, nitrate 3-5mg/L, pH 7.2, 3dKH.

The ammonia decreased on it's own before this water change so I'm getting somewhere. Changes this big every day? Umm, xxxx that, I'd tack the hoses to the ceiling from kitchen to lounge thru hall first!

What's a sponge filter?!!! (only joking, they have their uses)

I do keep discus but in more of a community setting rather than breeding rig...

Another lesson for me: when I get a pond set up, I'm going to be thinking about the filtration first then how to have 80% of the water ready at latest next day to change. Then heating/cooling/mass.

Or do you just stick a coldwater outside hose and dechlorinator in?! Anyone do that with several hundred gallons of tank/pond? Not sure I could due to the buffering needed.

Here's some pics in case you've all died of boredom...!

Best Regards,

Soggy

leiarius up 2 r.jpg

Leiarius eating whitebait r.jpg

leiarius dorsal.jpg

learius home 2 r.jpg

Leiarius up r.jpg
 
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