Hello; On the old silicone working with new questioin. I have tried to patch a leaking tank by adding new silicone over old, but seldom with success. It has worked a few times, but with ugly results and not great durability. It is sometimes worth a try.
For a number of years now, I have been cutting out all the old silicone possible and then resealing the whole thing at one time so that the new silicone is still tacky when it comes together at the corners.