I'm currently doing this for a new 90gal I'm setting up.
I tried using the 3/4" styrofoam layered from home depot but after cementing most of the detail was lost. so I tossed it out and am trying again with 2" thick styrofoam layered and carved down. Its overly thick but should let me have a couple caves for my featherfin cat and rainbow shark.
Also a note about ph, when I used 3/4" styrofoam, I figure I used about 1/3 of a 60lb bag. so I tested with 4oz of cured concrete in 2cups of water. It took 2 weeks of daily water changes before the test kit would even register the ph and not just be maxed out. I think the type of cement/concrete used may have an effect on ph as some mixes have more lime & limestone than standard portland cement.
I tried using the 3/4" styrofoam layered from home depot but after cementing most of the detail was lost. so I tossed it out and am trying again with 2" thick styrofoam layered and carved down. Its overly thick but should let me have a couple caves for my featherfin cat and rainbow shark.

Also a note about ph, when I used 3/4" styrofoam, I figure I used about 1/3 of a 60lb bag. so I tested with 4oz of cured concrete in 2cups of water. It took 2 weeks of daily water changes before the test kit would even register the ph and not just be maxed out. I think the type of cement/concrete used may have an effect on ph as some mixes have more lime & limestone than standard portland cement.