I would say that there is ~0 chance that those 5 shells will have any effect on your PH. When people on the web say that shells will change PH it is usually in reference to shell/crushed coral as a substrate which has 1,000x the surface area that you are questioning. There is no way that that amount of shell will have any impact on your 190 gallon tank.
On the other hand. Are you trying to make stingray-ka-bobs. Those shells look dangerous. They add like 10 different spikes to impale your hand, on top of the poisonous one on your rays.