Ordering fish online is relatively safe if the vendor takes the time to properly acclimate the fish and weather permits. Some people have had fish lost in transit for something like three days and still managed to keep the fish from passing. You will have to overnight which is going to be 50+ USD, and unless you are looking for showy pieces you likely won't get to pick them out. The nature of this makes it more efficient to do larger orders less frequently but if you don't have a good LFS within an hour of you it could be more efficient. I don't have personal experience with aquascape yet but I've heard nothing but good things so I wouldn't hesitate either.
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